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What episode is Hollow Ichigo arise?

I just saw episode 59 when Ichigo fight against Captain Kuchiki and half of his face mask becomes hollow and depression began to take control and fight. Therefore, when this happens again. Please give me the number of episodes. Oh, and for those of I think you'll skip these episodes are wrong. I could skip that expense is not necessary to watch it but all coming back to that later. Anyway, thanks in advance for responding.

I'm not sure about the number of episode, but it was when Urahara was training him. When he was locked in that deep huge hole, and becomes a hole, which is defended and gained shinigami powers, but the hollow part of his soul still exists, that comes out when Ichigo is the point of death.

HOW TO MAKE A HALF HOLLOW MASK part 1

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